Column-1 & 2 contain projection formula of some molecules & column-3 contains their properties.
Column 1 | Column 2 | Column 3 |
(I) | (i) | (P) Compounds having same boiling or melting points.
|
(II) | (ii) | (Q) Compuonds can be separated by fractional distillation.
|
(III) | (iii) | (R) Compounds having different boiling or melting points. |
(IV) | (iv) | (S) Compounds which are optical resolvable.
|
(i) The correct combination that represents enantiomers with their correct properties.
Text Solution
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(i) c (ii) d (iii) c
Sol. (i) to (iii)
(I) & (i) are enantiomers
(II) & (i) are identical compounds
(I) & (ii) are diastereomers
(III) & (iv) are meso compounds so they are identical
(IV) & (iii) are diastereomers
⇒ Enantiomers having same B.Pt or M.Pt so they can be separated by optical resolution.
⇒ Diastereomers having different B.Pt or M.Pt so they can be separated by Fractional distillation.
⇒ Mirror image of meso compound are identical & they have same BPt or MPt.
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