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CGP EDU Academic Team
Published on: August 12, 2026
The acidic hydrolysis of ether (X) shown below is fastest when

Text Solution
Verified by ExpertsThe correct answer is:
C
Ph 3 C–OR
Ph 3 C–OH + ROH
The reaction proceeds by S N 1 Mechanism :
Ph 3 C–OR + H ⊕
Ph 3 C
Ph 3 C ⊕ + ROH

Ph 3 C–OH
Ph 3 C– 
Greater the electron releasing effect of the attached groups greater is the stability of intermediate carbocation, & faster is the rate of reaction.
If two ph– groups are replaced by
groups, strong +M effect of MeO– groups stabilize, the carbocation better there by making the reaction faster.
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