For the non-stoichiometric reaction:
, the following kinetic data were obtained in three separate experiments, all at
.
| Initial | concentration |
| Initial | concentration |
| Initial rate of | formation of | ( mol L | |||||||||||
Initial | ||||||||||||||||||||
concentration | ||||||||||||||||||||
Initial | ||||||||||||||||||||
concentration | ||||||||||||||||||||
Initial rate of | ||||||||||||||||||||
formation of | ||||||||||||||||||||
( mol L | ||||||||||||||||||||
The rate law for the formation of
is
Text Solution
Verified by ExpertsA
: For the reaction, 
Rate of reaction 
Now, rate of reaction, 
From table,
(i)
(ii)
(iii)
On dividing equation (i) by (ii), we get


On dividing equation (i) by (iii), we get


Hence, 
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