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CGP EDU Academic Team
Published on: August 14, 2026
What happens when Mn(II) ions free from chloride ions react with acidified solution of (NH 4 ) 2 S 2 O 8 or K 2 S 2 O 8 in presence of a few drops of AgNO 3 solution ?
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Reddish–violet colouration is obtained owing to the formation of MnO 4 – .
2 Mn 2+ + 5 S 2 O 8 2– + 8 H 2 O
MnO 4 – + 10 SO 4 2– + 16 H +
AgNO 3 acts as catalyst.
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