Home Chemistry Alcohol, Phenol and Ether MHT CET Previous Year Question Isopropyl methyl ether when treated with col…
Chemistry Alcohol, Phenol and Ether MHT CET Previous Year Question Single Correct MCQ
Published on: August 12, 2026

Isopropyl methyl ether when treated with cold hydrogen iodide gives

A
isopropyl iodide and methyl iodide
B
isopropyl alcohol and methyl iodide
C
isopropyl alcohol and methyl alcohol
D
isopropyl iodide and methyl alcohol.

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Text Solution

Verified by Experts
The correct answer is:
B

: In case of unsymmetrical ethers having two different alkyl groups, the alcohol and the alkyl halide formed, depend on the nature of the alkyl groups. If primary and secondary alkyl groups are present, the reaction occurs by mechanism and because of steric hindrance, the halide ion attacks the smaller alkyl group and hence the alkyl halide is always formed from the smaller alkyl group.

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