A tertiary butyl carbocation is more stable than a secondary butyl carbocation because of
which of the following?
Text Solution
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Tertiary butyl carbocation Secondary butyl carbocation
(
atoms) (
atoms)
A tertiary butyl carbocation has 9 alpha hydrogen atoms whereas secondary butyl carbocation has 5 alpha hydrogen atoms. So when more number of
atoms is present, more will be the hyperconjugation effect hence more will be the stability of carbocation. Thus tertiary butyl carbocation is more stable than a secondary butyl carbocation due to hyperconjugation
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