Home Chemistry Haloalkanes and Haloarenes Skill Builder Which one of the following undergoes nucleop…
Chemistry Haloalkanes and Haloarenes Skill Builder Single Correct MCQ
Published on: August 13, 2026

Which one of the following undergoes nucleophilic aromatic substitution at the fastest rate?

A
B
C
D

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Text Solution

Verified by Experts
The correct answer is:
A

-I and -M group increases rate of reaction.

Nucleophilic aromatic substitution reaction is also known as reaction. To perform reaction benzene ring should have Positive charge on it self. As benzene ring has cloud therefore it self acts as a nucleophile in normal circumstances it cannot undergo reaction. The Essential condition for is "a strong electron withdrawing group must be present at directly attached position of the ring.

in this case group shows effect and generates +ve charge on the benzene ring. In this way Benzene ring behaves as an electrophile and a can easily attack on it to perform Ar reaction.
Mechanism.

Note- group should present at positions not at meta position to perform reaction.
The order of -M effect is

will undergo at fastest rate.

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