Given below are two statements:
Statement (I): p-Nitrophenol is more acidic than
-nitrophenol and o-nitrophenol.
Statement (II): Ethanol will give immediate turbidity with Lucas reagent.
In the light of the above statements, choose the correct answer from the options given below:
Text Solution
Verified by ExpertsD
: p-Nitrophenol is more acidic thar meta and ortho. isomers.
The electron withdrawing group,
stabilises the phenoxide ion through
effect at the ortho and para position. The effective delocalisation of negative charge in phenoxide ion enhance the acidic strength of phenols, The
group at meta position will show
effect only, The
group at ortho position forms hydrogen bond with -OH group.
Ethanol being primary alcohol does not react with Lucas reagent at room temperature. Tertiary alcohol will give turbidity immediately.
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