Home Chemistry Classification of Elements and Periodicity Ionisation Energy The formation of the oxide ion, O 2– (g), fr…
Chemistry Classification of Elements and Periodicity Ionisation Energy Single Correct MCQ
Published on: August 14, 2026

The formation of the oxide ion, O 2– (g), from oxygen atom requires first an exothermic and then an endothermic step as shown below:

O(g) + e – O – (g) ; Δ eg H = – 141 kJmol –1 O

– (g) + e – O 2– (g) ; Δ eg H = + 780 kJmol –1 Thus process of formation of O

2– in gas phase is unfavourable even though O 2– is isoelectronic with neon. It is due to the fact that:

A
oxygen is more electronegative.
B
addition of electron in oxygen results in larger size of the ion.
C
electron repulsion outweighs the stability gained by achieving noble gas configuration.
D
O – ion has comparatively smaller size than oxygen atom.

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The correct answer is:
C

There is electrostatic repulsion between the two species having same type of charge. So energy has to be given for the addition of additional electron to O – .

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