Home Chemistry Thermodynamics and Thermochemistry Free Energy and Work Function 1 mole of NH3 gas at 27 0 C is expanded in r…
Chemistry Thermodynamics and Thermochemistry Free Energy and Work Function Single Correct MCQ
Published on: August 14, 2026

1 mole of NH3 gas at 27 0 C is expanded in reversible adiabatic condition to make volume 8 times ( = 1.33). Final temperature and work done respectively are:

A
150 K, 900 cal
B
150 K, 400 cal
C
250 K, 1000 cal
D
200 K, 800 cal

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Text Solution

Verified by Experts
The correct answer is:
A

T 1 V 1 γ–1 = T 2 V 2 γ–1 300 × V 1/3 = T 2 (8V) 1/3

T 2 =150 K

W = nC v (T 2 – T 1 ) = 1 × 3 R (150 –300) = 3 × 2 (–150) = –900 cal

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