is a paramagnetic complex. Identify the INCORRECT statements about this complex.
Text Solution
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In
, Nickel is in +2 oxidation state.
has a
electronic configuration.
The complex is given as paramagnetic. For a 4 -coordinate
system, paramagnetism implies a tetrahedral geometry (
hybridization) with two unpaired electrons.
Statement A: Tetrahedral complexes of the type
do not exhibit geometrical isomerism because all positions are adjacent to each other. Thus, A is incorrect.
Statement B: Most
complexes are colored due to
transitions.
is a dark blue/green crystalline solid, not white. Thus, B is incorrect.
Statement C: With 2 unpaired electrons, the spin-only magnetic moment
. Thus, C is correct.
Statement D: For a tetrahedral complex with
configuration, the CFSE is calculated as
. The statement mentions
, which is incorrect as the complex is tetrahedral, not octahedral. Thus, D is incorrect.
Statement E:
is a tetrahedral complex (
hybridization). Since
is also tetrahedral, their geometrical arrangements are similar. Thus, E is correct.
The incorrect statements are A, B, and D.
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