Home Chemistry Electrochemistry JEE Advanced Previous Years Question The standard electrode potential E Θ and its…
Chemistry Electrochemistry JEE Advanced Previous Years Question Single Correct MCQ
Published on: August 14, 2026

The standard electrode potential E Θ and its temperature coefficient for a cell are 2 V and –5 × 10 –4 VK –1 at 300 K respectively. The cell reaction is

Zn(s) + Cu 2+ (aq) → Zn 2+ (aq) + Cu(s)

The standard reaction enthalpy ( Δ r H Θ ) at 300 K in kJ mol –1 is:

(Use R = 8JK –1 mol –1 and F = 96,000 Cmol –1 )

A
206.4
B
–384.0
C
192.0
D
–412.8

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Text Solution

Verified by Experts
The correct answer is:
D

Δ H = – nFE cell + nFT

= –2 × 96000 × 2 + 2 × 96000 × 300 × (–5 × 10 –4 )

= – 384000 – 28,800

= – 412.8 kJ/mol

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