For a reaction, A
P, the plots of [A] and [P] with time at temperatures T 1 and T 2 are given below.

If T 2 > T=, the correct statement(s) is (are) (Assume
and
are independent of temperature and ratio of lnK at T 1 to lnK at T 2 is greater than T 2 /T 1 . Here H, S, G and K are enthalpy, entropy, Gibbs energy and equilibrium constant, respectively.)
Text Solution
Verified by ExpertsCHECK THE SOLUTION.
(a, c)






(exothermic)
H° < 0, since (P) at T 2 < at T 1
G° =
H° - T
S°
T
S° =
H° -
G°


Also, 


It is possible only if
S 0 < 0.
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