Consider the following statements about
- and
-block elements.
(I) The colour of
is due to
transition.
(II) Actinides have larger number of oxidation states than lanthanides.
(III) Tripositive ions of Pr (At. no.
) and
(At. no.
) have the same (green) colour.
(IV) Actinides have magnetic moments less than theoretically predicted values.
(V)
and
-orbitals are equally shielded.
Choose the correct option.
Text Solution
Verified by ExpertsA
Statements II, III and IV are true while I and V are false. In
, the colour is due to charge transfer and not
transition. Actinides exhibit a larger number of oxidation states than lanthanides because there is a very small energy gap between
, and
orbitals.
has two
electrons (both unpaired).
has twelve
electrons (5 pairs and 2 unpaired). Both
and
with 2 unpaired electrons each, have the same colour.
electrons in actinides are less effectively shielded resulting in quenching of orbital contribution of magnetic moments. So their magnetic moments are less than theoretically predicted values. Though,
and
-orbitals have similar shapes but
is less deeply buried than
. Hence, electrons in
-orbital can participate in bonding to a far greater extent than electrons in
-orbital. Therefore, shielding of
-orbital is more than
-orbital.
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