An alkene "A" on ozonolysis (
, then
) furnishes propanone and ethanal in a
ratio. When HCl is added to " A ", the major product " B " is obtained. Which structure corresponds to " B "?
Text Solution
Verified by ExpertsThe correct answer is:
A
Ozonolysis giving propanone + ethanal implies the alkene is 2 -methyl-2-butene.
(
) because each C of
becomes the carbonyl of those fragments. Addition of HCl to an unsymmetrical alkene follows Markovnikov's rule (electrophilic addition): Cl goes to the more substituted
2-chloro-2-methylbutane, structure .
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