Home Chemistry Solid State General The structure of a crystalline lattice AB is…
Chemistry Solid State General Single Correct MCQ
Published on: August 14, 2026

The structure of a crystalline lattice AB is rock salt type where B atoms are occupying all the CCP positions but A atoms are occupying all the octahedral voids -

A
If atoms lying on one tetrad axis of symmetry are removed then molecular formula of the compound become AB
B
If atoms lying on one triad axis of symmetry are removed then molecular formula of the compound become A4B5
C
If atoms lying on one diad axis of symmetry are removed then molecular formula of the compound become A5B8
D
All of the above molecular formula are correct corresponding to the defects mentioned

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Text Solution

Verified by Experts
The correct answer is:
D

The no. of A atoms remaining = 4 – 1 = 3

The no. of B atoms remaining = 4 – 2 ×

= 4 – =

Molecular formula is A 3 B 15/4 ≡ A 12 B 15 ≡ A 4 B 5

The no. of A atoms

= 4 – 1 – 2 ×

= 4 – =

The no. of B atoms = 4

Molecular formula A 5/2 B 4 or A 5 B 8

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