The increasing order of Ag + ion concentration in
I. Saturated solution of AgCl
II. Saturated solution of AgI
III. 1(M) Ag(NH 3 ) 2 + in 0.1 (M) NH 3
IV. 1(M) Ag(CN) 2 – in 0.1 (M) KCN
Given: K sp of AgCl = 10 –10 ;K sp of AgI = 10 –16
K instab of Ag(NH 3 ) 2 + = 10 –8
K instab of Ag(CN) 2 – = 10 –21
Text Solution
Verified by ExpertsC
In saturated solution AgCl, [Ag + ] = 10 –5 (M)
In saturated solution AgI ,[Ag + ] = 10 –8 (M)
In the solution containing Ag(NH 3 ) 2 + & NH 3 ,
10 –8 =
or [Ag + ] = 10 –6 (M)
In the solution containing Ag(CN) 2 – & KCN
10 –21 =
or [Ag + ] = 10 –19 (M)
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