Home Chemistry Chemical Kinetics Statement Based The reaction of NO2 (g) and O3 (g) is first-…
Chemistry Chemical Kinetics Statement Based Single Correct MCQ
Published on: August 14, 2026

The reaction of NO2 (g) and O3 (g) is first-order in NO2 (g) and O3 (g)

2 NO2 (g) + O3 (g) N2O5 (g) + O2 (g)

The reaction can take place by mechanism :

I : NO2 + O3 NO3 + O2

NO3 + NO2 N2O5

II : O3 O2 + [O]

NO2 + O NO3

NO3 + NO2 N2O5

Select correct mechanism.

A
I only
B
II only
C
Both I and II
D
None of I and II

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Text Solution

Verified by Experts
The correct answer is:
C

For Rxn rate determining step is slowest step

Then in 1st Rxn

.....(i)

But 2nd Rxn

O3 O2 + [O]....

NO2 + O NO3 ....

NO3 + NO2 N2O5 ....

Then for Rxn

....

by Rxn

....(ii)

put value of [O] from to (ii)

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