Published by:
CGP EDU Academic Team
Published on: August 14, 2026
The standard emf of the cell
Zn | Zn +2 (aq) || Fe +2 | Fe +3 (aq) | Pt
is 1.534 V at 25ºC and 1.576 V at 65ºC.
(i) The value of Δ Hº at 25ºC is –
Correct Answers for Comprehension Sub-Questions
Text Solution
Verified by ExpertsThe correct answer is:
CHECK THE SOLUTION.
(i)
Sol. – 356 KJ mol –1
(ii)
Sol. – 202 J K –1 mol –1 (iii)
Sol. At 25ºC,
Dg Δ Gº = – nFEº = – 296 Kj mol
–1 At 65ºC
Δ Gº = – 304 kJ mol
–1 ∴ At 25º
Δ Gº = – RT lnK ⇒ ln K = 119
Δ Sº = –
= – 202 JK
–1 mol –1 Δ Hº = Δ Gº + T Δ Sº = – 356 KJ mol
–1
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