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CGP EDU Academic Team
Published on: August 13, 2026
Consider the cell : Ag | AgCl (s) | KCl (1M) | Hg 2 Cl 2 (s) | Hg ( λ ) | Pt. The cell potential :
Text Solution
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(c, d)
RHE reaction :
Hg 2 Cl 2 (s) + 2e ⎯→ 2Hg( λ ) + 2Cl –
LHE reaction :
2Ag(s) + 2Cl – ⎯→ 2AgCl(s) + 2e
Net reaction :
Hg 2 Cl 2 (s) + 2Ag(s) ⎯→ 2Hg ( λ ) + 2AgCl(s)
In case of same concentration of Cl – ions in the two half cells, E cell is independent on the concentration of Cl – . Other substances are either pure solids or liquids, which have unit activities irrespective of their amounts.
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