Home Chemistry Co-ordinatios Compounds General The crystal field splitting energy for octah…
Chemistry Co-ordinatios Compounds General Single Correct MCQ
Published on: August 13, 2026

The crystal field splitting energy for octahedral complex ( Δ o) and that for tetrahedral complex ( Δ t ) are related as:

A
Δ t = Δ 0
B
Δ t = 0.5 Δ o
C
Δ t = 0.33 Δ o
D
Δ t= Δ 0

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Text Solution

Verified by Experts
The correct answer is:
A

this may attributes to the following two reasons.

(i) there are only four ligands instead of six, so the ligand field is only two thirds the size ; as the ligand field splitting is also the two thirds the size and (ii) the direction of the orbitals does not concide with the direction of the ligands. this reduces the crystal field splitting by roughly further two third.

So Δ t = × = Δ o.

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