Home Chemistry Aldehydes, Ketones & Carboxylic Acid General Carboxylic acids having at least one α -hydr…
Chemistry Aldehydes, Ketones & Carboxylic Acid General Comprehension
Published on: August 13, 2026

Carboxylic acids having at least one α -hydrogen react with Cl2 or Br2 in the presence of phosphorus (or a phosphorus halide) to give α -halo acids. This reaction is known as Hell-Volhard-Zelinsky reaction (HVZ reaction),

R–CH2–COOH

The HVZ reaction is limited to the formation of α -chloro and α -bromo acids and it is sometimes awkward to carry out. The reagents (X2 and P) are noxious and the reaction time is often long and the conditions of reaction are harsh.

(i)Which of the following carboxylic acids will not give HVZ reaction ?

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The correct answer is:
CHECK THE SOLUTION.

(i)

Sol.

(ii)

Sol. All of these

(iii)

Sol.

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