Home Chemistry Alcohol, Phenol and Ether General Ortho-nitrophenol is less soluble in water t…
Chemistry Alcohol, Phenol and Ether General Single Correct MCQ
Published on: August 12, 2026

Ortho-nitrophenol is less soluble in water than p- and m-nitrophenols because

A
o-nitrophenol shows intramolecular H-bonding
B
o-nitrophenol shows intermolecular H-bonding
C
Melting point of o-nitrophenol is lower than those of m- and p-isomers
D
o-nitrophenol is more volatile in steam than those of m- and p-isomers

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The correct answer is:
A

o-Nitrophenol is stable due to intramolecular hydrogen bonding.

It is difficult to break the H-bonding when dissolved in water thus less soluble.

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