SN1 reaction underoges through a carbocation intermediate as follows : -

[R = t-Bu, iso-Pr, Et, Me] (X = Cl, Br, I)
The correct statements are
I. The decreasing order of rate of SN1 reaction is t-BuX > iso-PrX > EtX > MeX
II. The decreasing order of ionisation energy is MeX > EtX > iso-PrX > t-BuX
III. The decreasing order of energy of activation is t-BuX >
iso-PrX >EtX > MeX
Text Solution
Verified by ExpertsA
Rate of SN1 reaction is a
t Bu X > iso - PrX > EtX > MeX
So order of activation energy
t – BuX < iso PrX < EtX < MeX
order of ionisation energy
t BuX < iso PrX < EtX < MeX
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