Match the following two column for electrophillic addition reaction of alkene :
Column-I | Column-II |
(i) Over all addition of H2O | [A] Addition of Br2/H2O |
(ii) Electrophile H+ (in RDS) | [B] Addition of HBr (in absence of peroxide) |
(iii) Electrophile Br+ (in RDS) | [C] Attack of Br2/CCl4 |
(iv) Possibility of rearrangement | [D] Oxymercuration – Demercuration |
[E] Acidic hydration of alkene |
Text Solution
Verified by Experts(i) [D]; (ii) [B]; (iii) [A]; (iv) [B]
(i) [D],[E]
(ii) [B],[E]
(iii) [A],[C]
(iv) [B],[E]
Sol.
(i) Oxymercuration – Demercuration, Acidic hydration
of alkene
(ii) Addition of HBr (in absence of peroxide), Acidic
hydration of alkene
(iii) Addition of Br 2 /H 2 O, Attack of Br 2 /CCl 4
(iv) Addition of HBr (in absence of peroxide), Acidic
hydration of alkene
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