The bromination of acetone that occurs in acid solution is represented by this equation.
These kinetic data were obtained for given reaction concentrations.
Initial concentrations, |
| |
|
|
|
0.30 | 0.05 | 0.05 |
0.30 | 0.10 | 0.05 |
0.30 | 0.10 | 0.10 |
0.40 | 0.05 | 0.20 |
Initial rate, disappearance of




3.1 
Based on these data, the rate equation is
Text Solution
Verified by ExpertsC
From the first two experiments, it is clear that when concentration
is doubled, the initial rate of disappearance of
remains unaltered. So, order of reaction with respect to
is zero. The probable rate law for the reaction will be : 
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