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Chemistry Chemical Analysis Previous Year Questions Single Correct MCQ
Published on: August 14, 2026

Sodium salt of an organic acid ‘X’ produces effervescence with conc. H 2 SO 4 . ‘X’ reacts with the acidified aqueous CaCl 2 solution to give a white precipitate which decolourises acidic solution of KMnO 4 . ‘X’ is :

A
HCOONa
B
CH 3 COONa
C
Na 2 C 2 O 4
D
C 6 H 5 COONa

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Verified by Experts
The correct answer is:
C

Na 2 C 2 O 4 + H 2 SO 4 ⎯→ Na 2 SO 4 + H 2 O + CO + CO 2

Na 2 C 2 O 4 + CaCl 2 ⎯→ CaC 2 O 4 ↓ + 2NaCl

8H 2 SO 4 + 5CaC 2 O 4 + 2KMnO 4 ⎯→ 5CaSO 4 + K 2 SO 4 + 2MnSO 4 + 8H 2 O + 10CO 2

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