Match List I with List II
List I List II
A. Benzenesulphonyl chloride I. Test for primary amines
B. Hoffmann bromamide reaction II. Anti Saytzeff
C. Carbylamine reaction III. Hinsberg reagent
D. Hoffmann orientation IV. Known reaction of Isocyanates.
Choose the correct answer from the options given below:
Text Solution
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Hinsberg reagent
Benzen sulphonyl chloride
Hoffmann bromamide reaction
known reaction of isocynates
R-CO-NH 2 + X 2 + 4 NaOH
R-NH 2 + 2NaX + Na 2 CO 3 + 2H 2 O
Intermediate : R- N = C = O (isocyanate)
Carbylamine reaction
Test for primary amine
R-NH 2 or Ar - NH 2 + CHC1 3 + 3KOH
RNC or Ar - NC+ 3KC1 + 3H 2 O
Hoffmann orientation
Anti saytzeff
(Formation of less substituted alkene as major product)
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