Home Chemistry General Organic Chemistry JEE (Main) / AIEEE Problems (Previous Year) An unknown alochol is treated with the “Luca…
Chemistry General Organic Chemistry JEE (Main) / AIEEE Problems (Previous Year) Single Correct MCQ
Published on: August 13, 2026

An unknown alochol is treated with the “Lucas reagent” to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism :

A
secondary alcohol by S N 1
B
tertiary alcohol by S N 1
C
secondary alcohol by S N 2
D
tertiary alcohol by S N 2

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Text Solution

Verified by Experts
The correct answer is:
B

The reaction of alcohol with lucas reagent is mostly an S N 1 reaction and the rate of reaction is directly proportional to the carbocation stability formed in the reaction, since 3° R–OH forms 3° carbocation hence it will react fastest.

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