The analysis of three different binary oxides of bromine (Br) and oxygen (O) gives the following results:
Compound | Mass of O combined with 1.0 g of Br |
X | 0.101 g |
Y | 0.303 g |
Z | 0.503 g |
Which of the following statements is not correct?
(I) Compound Y is Br 2 O 3
(II) Compound Z is Br 2 O 5
(III) Compound Z is Br 2 O 7
(IV) Compound Y is Br 2 O 5
Text Solution
Verified by ExpertsC
1.Determine the mass ratios:
For compound
: Mass of
combined with
of 
For compound
: Mass of
combined with
of 
For compound Z: Mass of O combined with
of 
2. Convert mass ratios to molar ratios using atomic masses:
Atomic mass of 
Atomic mass of 
3. Calculate the moles of oxygen per mole of bromine for each compound:
For compound X:
Moles of
Moles of
Mole ratio
Therefore, the empirical formula for
is
.
For compound
:

Moles of 
Mole ratio
Therefore, the empirical formula for
is
,
For compound Z:
Moles of
Moles of
Mole ratio
Therefore, the empirical formula for
is
.
Now, let's verify the statements:
I. Compound
is Br2O3: Correct
II. Compound
is
: Correct
III. Compound
is
: Incorrect
IV. Compound
is
: Incorrect
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