Chemistry Gaseous State ( Not In Syllabus ) JEE Advanced Previous Years Question Single Correct MCQ
Published on: August 13, 2026

The van der Waals equation for one mole of a real gas can be written as

(P + a/V 2 ) (V – b) = RT. For the gases H 2 , NH 3 , and CH 4 , the value of 'a' (bar L –2 mol –2 ) are

0.2453, 4.170 and 2.253 respectively.

Which of the following can be inferred from the 'a' values ?

A
NH 3 can be most easily liquified
B
H 2 can be most easily liquified
C
value of 'a' for CH 4 is less than that of NH 3 because it has the lower molar mass
D
intermolecular forces are the strongest in hydrogen

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Verified by Experts
The correct answer is:
A

van der Wall's constant 'a' gives information about force of attraction between gaseous molecules.. Higher the value of 'a' higher will be force of attraction, and easier the liquefaction of gas.Order of intermolecular force of attraction = H 2 < CH 4 < NH 3 .

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