Which one of the following information about the compounds is correct ?
Compounds | Oxidation state of P | No. of P–OH bonds | No. of P–H bonds | No. of P=O bonds |
[I] H3PO2 Hypophosphorous acid | 1+ | 2 | 1 | 0 |
[II] H4P2O5 pyropophosphorous acid | 3+ | 2 | 2 | 2 |
[III] H4P2O6 Hypophosphoric acid | 4+ | 2 | 2 | 2 |
[IV] H4P2O7 pyrophosphoric acid | 5+ | 3 | 1 | 4 |
Text Solution
Verified by ExpertsD
(I) H 3 PO 2 → 
Oxidation state of P = +1
No. of P-OH bond = 1
No. of P–H bond = 2
No. of P=O bond = 0
⇒ option is incorrect.
(II) H 4 P 2 O 5 → 
Oxidation state of P = +3
No. of P-OH bond = 2
No. of P–H bond = 2
No. of P=O bond = 2 ⇒ correct option is II.
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