Chemistry S and P - Block Elements (S - Block Elements Not In Syllabus ) Compounds of Carbon and Silicon Single Correct MCQ
Published on: August 11, 2026

What is/are not true about phosphine (PH 3 ) ?

A
It turns red litmus blue.
B
It reacts with HCl (aq.) to give PH 4 Cl.
C
Phosphonium compounds are obtained when anhydrous phosphine reacts with anhydrous HBr or HI.
D
It is prepared by hydrolysis of metal phosphides with acids.

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CHECK THE SOLUTION.

(a,b)

PH 3 is a lewis base but is neutral towards red litmus.

It does not react with HCl(aq) or HI(aq). This is because water decomposes PH 4 X formed to give back PH 3 .

It reacts only with anhydrous HI or HBr.

2Na 3 P + 3H 2 SO 4 ⎯→ 3Na 2 SO 4 + 2PH 3 ; Ca 3 P 2 + 6HCl ⎯→ 3CaCl 2 + 2PH 3

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