Home Chemistry Solution & Colligative Properties General The vapor pressures of chlorobenzene and wat…
Chemistry Solution & Colligative Properties General Single Correct MCQ
Published on: August 14, 2026

The vapor pressures of chlorobenzene and water at different temperatures are

t/°C

90

100

110

P°(φCl)/ mm Hg

204

289

402

P°(H2O)/mmHg

526

760

1075

At what temperature will φ Cl steam-distillation under a total pressure of 800 mmHg?

A
95ºC
B
92ºC
C
94ºC
D
89ºC

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Text Solution

Verified by Experts
The correct answer is:
A

At 90ºC, Total P T = 730 mm Hg

At 100ºC total P T = 289 + 760 = 1049 mm Hg

so for 800 mm Hg, temperature will lie in between 90º –100ºC

Using extrapolation method, Temperature = 90 + × (100 – 90) = 92.19ºC.

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