Home Chemistry Solid State General In a crystalline solid having molecular form…
Chemistry Solid State General Single Correct MCQ
Published on: August 12, 2026

In a crystalline solid having molecular formula A 2 B anion

A
are equally distributed between octahedral and tetrahedral voids. (i) What percentage of octahedral voids is occupied? (ii) What percentage of tetrahedral voids is occupied? Report your answer ((i) – (ii)).
B
are arranged in cubic close packed lattice and cations

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Text Solution

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The correct answer is:
CHECK THE SOLUTION.

50 = (100 – 50)

Sol. Number of octahedral void in ccp = Z; Number of tetrahedral void in ccp = 2Z.

For A 2 B, Number of anion B = 4.

Cataion present in all octahedral void (100% occupied) and half tetrahedral void (50% occupied), then number of cation in unit cell = 4 + 8 × = 8.

So, formula of compound = A 2 B.

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