Home Chemistry Electrochemistry JEE Advanced Previous Years Question Given below are the half-cell reactions : Mn…
Chemistry Electrochemistry JEE Advanced Previous Years Question Single Correct MCQ
Published on: August 12, 2026

Given below are the half-cell reactions :

Mn 2+ + 2e – ⎯→ Mn ; Eº = –1.18 V

2(Mn 3+ + e – ⎯→ Mn 2+ ) ; Eº = +1.51 V

The Eº for 3Mn 2+ ⎯→ Mn + 2Mn 3+ will be :

A
–2.69 V ; the reaction will not occur
B
–2.69 V ; the reaction will occur
C
–0.33 V ; the reaction will not occur
D
–0.33 V ; the reaction will occur

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Text Solution

Verified by Experts
The correct answer is:
A

Mn 2+ Mn

∴ for Mn 2+ disproportionation, E 0 = – 1.51 V –1.18 V

= – 2.69 V < 0

Reaction is non-spontaneous.

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