Home Chemistry Electrochemistry General The standard oxidation potential for the hal…
Chemistry Electrochemistry General Subjective Type
Published on: August 13, 2026

The standard oxidation potential for the half − cell

NO 2 – (g) + H 2 O ⎯→ NO 3 − (aq) + 2H + (aq) +2e is − 0.78 V.

Calculate the reduciton potential in 9 molar H + assuming all other species at unit concentration. What will be the reduction potential in neutral medium ?

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The correct answer is:
CHECK THE SOLUTION.

0.836 volt, 1.1937 volt

Sol. E oxidation = – 0.78 – log 9 2 = – 0.78 – × 2 × log 9 = –0.836 volt

E reduction = –E oxidation = 0.836 volt

In neutral medium,

E Oxidation = – 0.78 – log (10 –7 ) 2 = –1.1937 volt

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