Which kind of isomerism is shown by the complex [Co(NH 3 ) 5 (ONO)]SO 4 ?
1. Ionisation isomerism
2. Linkage isomerism
3. Geometrical isomerism
4. Optical isomerism
Text Solution
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NO 2 – is an ambidentate ligand and can link to central metal ion either through N or O. Hence it show linkage isomerism. There is exchange of NO 2 – and SO 4 2– occurs between coordination sphere and ionization sphere. Hence it shows ionisation isomerism. Ma 5 b has only one form, therefore, it does not show geometrical isomerism. Ma 5 b has mirror plane, therefore, it does not show optical isomerism.
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