Home Chemistry General Organic Chemistry JEE ADVANCED Previous Year Question Match the compounds/ions in Column I with th…
Chemistry General Organic Chemistry JEE ADVANCED Previous Year Question Subjective Type
Published on: August 13, 2026

Match the compounds/ions in Column I with their properties/reactions in Column II.

Column-I

Column-II

(a)

C6H5CHO

(p)

gives precipitate with 2,4 dinitrophenylhydrazine.

(b)

CH3CCH

(q)

gives precipitate with AgNO3.

(c)

CN

(r)

is a nucleophile.

(d)

Ι

(s)

is involved in cyanohydrin formation.

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Text Solution

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The correct answer is:
CHECK THE SOLUTION.

– (p, q, s) ; – (q) ; – (q, r, s) ; – (q, r)

Sol . (p) 2, 4-DNP (2, 4-dinitrophenyl hydrazine) is used to distirguish carbonyl compounds as it gives solid orange precipitate of 2,4-dinitrophenyl hydrazone.

(q) Tollen’s reagent (ammonical silver nitrate solution) gives white precipitate with alkyne and silver mirror test with aldehyde.

(r) (i) will gives AgCN with AgNO 3 (ii) is nucleophile (iii) forms cyanohydrin

(s) (i) will give Ag I with AgNO 3 (ii) is nuclophile

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