The Total pressure observed by mixing two liquid A and B is 350 mm Hg when their mole fractions are 0.7 and 0.3 respectively.
The Total pressure becomes 410 mm Hg if the mole fractions are changed to 0.2 and 0.8 respectively for A and B. The vapour pressure of pure A is______mm Hg. (Nearest integer)Consider the liquids and solutions behave ideally,
Text Solution
Verified by Experts314
(314)
Let V.P. of pure A be 
Let V.P of pure B be 
When X A =0.7 &X B =0.3
P s = 350
x0.7 +
x0.3 = 350 ...(i)
When X A =0.2&X B =0.8
P s =410
x0.2 +
x0.8 = 410 ...(ii)
Solving (i) and (ii)
=314mmHg
= 434 mm Hg
=(314)
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