The correct order of reactivity of the following benzyl halides towards reaction with KCN is:

Text Solution
Verified by ExpertsB
Reactivity in SN 2 reactions with KCN depends on the stability and nucleophilicity of the transition state.
For benzyl halides, substituents on the benzene ring affect the reactivity of the benzylic carbon through resonance and inductive effects.
Para-nitro group (-NO 2 ) is strongly electron-withdrawing, activating the benzylic carbon toward nucleophilic substitution.
Para-amino (-NH 2 ) is electron-donating, deactivating.
Para-hydroxyl (-OH) is weakly donating.
Meta-nitro group has reduced electron-withdrawal compared to para-position.
Order of reactivity based on electronic effects: para-NO 2 > meta-NO 2 > para-OH > para-NH 2 .
This gives 
Prepare Smarter with CGP Edu
Get practice questions, solutions, and test series in one place.
Write a Review
Share your experience with this question and solution.
Commentary
Send your comment, doubt, correction, or feedback to admin.
Similar Questions
Explore conceptually related problems