Published by:
CGP EDU Academic Team
Published on: August 13, 2026
The correct order of the rate of reaction of the following reactants with nucleophile by SN1 mechanism is: (Given: Structure I and II are rigid)
(I) (II)

(III) (IV)
Text Solution
Verified by ExpertsThe correct answer is:
D
Rate of
Stability of
formed
(I) and (II) are unstable due to Bredt's rule, (I) has more + I effect.
(II)
(I)
(III)
(IV)
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(I)
(II)
(IV)
(III)
(II)
(I)
(II)
(III)
(IV)
(I)
(III)
(IV)