As compared with chlorocyclohexane, which of the following statements correctly apply to chlorobenzene?
, ,
bond has partial double bond character. , ,
bond is less polar. and (E) Only
and (E) Only
and
bond is longer due to repulsion between delocalised electrons of the aromatic ring and lone pairs of electrons of chlorine. (E) The
bond is formed using 
hybridised orbital of carbon. Choose the correct answer from the options given below: and (E) Only
Only
Text Solution
Verified by ExpertsA
Chlorobenzene has Cl attached to an 
carbon of the benzene ring, while chlorocyclohexane has Cl attached to an 
carbon.
Statement B is correct: the C-Cl bond has partial double bond character due to resonance with the aromatic 
system, where chlorine's lone pairs interact with the aromatic ring.
Statement C is correct: the 
bond is less polar in chlorobenzene because the resonance contribution reduces the electronegativity difference between C and Cl .
Statement E is correct: the 
bond is formed using 
hybridized orbital of carbon.
Statement A is incorrect because chlorine carries less negative charge due to resonance donation to the aromatic system.
Statement D is incorrect because the 
bond is actually shorter in chlorobenzene due to partial double bond character, not longer.
The correct statements are B, C, and E only.
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