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Chemistry Thermodynamics and Thermochemistry General Single Correct MCQ
Published on: August 14, 2026

Heat of combustion of ethanol at constant pressure and at 298 K is found to be –Q kJ mol –1 . Hence, heat of combustion of ethanol at the same temperature at constant volume will be

A
(–Q + RT) kJ mol -1
B
(–Q – RT) kJ mol -1
C
(+Q - RT) kJ mol -1
D
(Q + RT) kJ mol -1 .

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Text Solution

Verified by Experts
The correct answer is:
B

C 2 H 5 OH + 3O 2 ⎯→ 2CO 2 + 3H 2 O

X = –Q + Δ nRT Δ n = –1

X = –Q – RT

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