A → product (First order reaction). Three sets of experiment were performed for a reaction under similar experimental conditions:
Run
of 10 M solution of reactant A
Run
of 10 M solution of reactant A
Run
of 10 M solution of reactant
of
added.
The correct variation of rate of reaction is
Text Solution
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For a first-order reaction, rate
, where rate is directly proportional to reactant concentration.
Run 1: 100 mL of 10 M solution
Concentration
Rate:
Run 2: 200 mL of 10 M solution
Concentration remains 10 M (increasing volume doesn't change concentration)
Rate:
Therefore
Run 3: 100 mL of 10 M solution +100 mL of
Total moles of
Total volume
New concentration
Rate:
Therefore 
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