Home Chemistry Aldehydes, Ketones & Carboxylic Acid JEE Main 2026 An organic compound " P " of molecular formu…
Chemistry Aldehydes, Ketones & Carboxylic Acid JEE Main 2026 Single Correct MCQ
Published on: August 14, 2026

An organic compound " P " of molecular formula gives positive Iodoform test but negative Tollen's test. When " P " is treated with dilute acid, it produces " Q ". " Q " gives positive Tollen's test and also iodoform test. The structure of " P " is:

A

B
C

D

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Text Solution

Verified by Experts
The correct answer is:
A

P gives positive iodoform (has ) but negative Tollen's (no -CHO).

Q (after acid hydrolysis) gives both tests, meaning Q has both and -CHO .
This indicates P has an acetal protecting an aldehyde group.
Option :
Has positive iodoform
Has acetal , no free aldehyde → negative Tollen's
Hydrolysis:
gives both iodoform and Tollen's test
Molecular formula:

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