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CGP EDU Academic Team
Published on: August 14, 2026
The enthalpy of vapourisation of water = 45.953 kJ/mol. At 1 atm pressure the boiling point of water is 373 K. What is the boiling point of water when pressure equal to ½ atm in Kelvin in nearest possible integers? Given : log 2 = 0.3
Text Solution
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0356
Sol. log
=

log
=

= 2.4 × 10 3 × 
p 2 =
atm, p 1 = 1 atm
log
= 2.4 × 10 3 × 
= – log 2
∴ 2.4 × 10 3 ×
= – 0.3
–
= –
× 10 –3
= – 0.125 × 10 –3
or
+ 0.125 × 10 –3 = 
or
= 2.681 × 10 –3 + 0.125 × 10 –3
= 2.806 × 10 –3 or T 2 =
= 356.38 K ~ 356 K
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