Home Chemistry Thermodynamics and Thermochemistry Heat of Reaction The enthalpy of vapourisation of water = 45.…
Chemistry Thermodynamics and Thermochemistry Heat of Reaction Subjective Type
Published on: August 14, 2026

The enthalpy of vapourisation of water = 45.953 kJ/mol. At 1 atm pressure the boiling point of water is 373 K. What is the boiling point of water when pressure equal to ½ atm in Kelvin in nearest possible integers? Given : log 2 = 0.3

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The correct answer is:
CHECK THE SOLUTION.

0356

Sol. log =

log =

= 2.4 × 10 3 ×

p 2 = atm, p 1 = 1 atm

log = 2.4 × 10 3 ×

= – log 2

∴ 2.4 × 10 3 × = – 0.3

= – × 10 –3

= – 0.125 × 10 –3

or + 0.125 × 10 –3 =

or = 2.681 × 10 –3 + 0.125 × 10 –3

= 2.806 × 10 –3 or T 2 = = 356.38 K ~ 356 K

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