Home Chemistry Co-ordinatios Compounds JEE (Main) / AIEEE Problems (Previous Year) Which of the following facts about the compl…
Chemistry Co-ordinatios Compounds JEE (Main) / AIEEE Problems (Previous Year) Single Correct MCQ
Published on: August 13, 2026

Which of the following facts about the complex [Cr(NH 3 ) 6 ]Cl 3 is wrong ?

A
The complex involves d 2 sp 3 hybridisation and is octahedral in shape.
B
The complex is paramagnetic.
C
The complex is an outer orbital complex.
D
The complex gives white precipitate with silver nitrate solution.

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Text Solution

Verified by Experts
The correct answer is:
C

In case of d 3 configuration, the number of unpaired electrons remains 3 whether the ligand is strong field or weak field. The hybridisation scheme can be shown as follow :

[Cr(NH 3 ) 3 ] 3+ =

Hence the complex is inner orbital complex as it involves (n – 1) d orbitals for hybridisation,

3.93 = ; so n = 3 (here n is number of unpaired electron(s)).

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