Home Chemistry Co-ordinatios Compounds JEE (Main) / AIEEE Problems (Previous Year) The magnetic moment (spin only) of [NiCl 4 ]…
Chemistry Co-ordinatios Compounds JEE (Main) / AIEEE Problems (Previous Year) Single Correct MCQ
Published on: August 13, 2026

The magnetic moment (spin only) of [NiCl 4 ] 2– is :

A
1.82 BM
B
5.46 BM
C
2.82 BM
D
1.41 BM

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Text Solution

Verified by Experts
The correct answer is:
C

In the paramagnetic and tetrahedral complex [NiCl 4 ] 2– , the nickel is in +2 oxidation state and the ion has the electronic configuration 3d 8 . The hybridisation scheme is as shown in figure.

Ni 2+ , [Ar]3d 8

[NiCl 4 ] 2–

sp 3 hybrid orbitals

μ B.M. = = = = 2.82 BM

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