Write the expressions for equilibrium constant K C and K P and classify in Homogeneous and Hetereogeneous equilibrium :
(i) N 2 O 4 (g) 
2NO 2 (g)
(ii) 3Fe(s) + 4H 2 O(g) 
Fe 3 O 4 (s) + 4H 2 (g)
(iii) NH 4 HS(s) 
NH 3 (g) + H 2 S(g)
(iv) CH 3 COOH( λ ) + C 2 H 5 OH( λ ) 
CH 3 COOC 2 H 5 ( λ ) + H 2 O( λ )
(v) MgCO 3 (s) 
MgO(s) + CO 2 (g)
(vi) 2H 2 S(g) 
2H 2 (g) + S 2 (g)
(vii) SO 2 (g) + NO 2 (g) 
SO 3 (g) + NO(g)
(viii) NH 4 NO 2 (s) 
N 2 (g) + 2H 2 O( λ )
Text Solution
Verified by ExpertsCHECK THE SOLUTION.
(i) Homogeneous equilibrium 
(ii) Hetereogeneous equilibrium 
(iii) Hetereogeneous equilibrium K C = [NH 3 ] [H 2 S] K P = (P NH 3 ) (P H 2 S )
(iv) Homogeneous equilibrium
but K P is not define for liquid system
(v) Hetereogeneous equilibrium K C = [CO 2 ] K P = (P CO 2 )
(vi) Homogeneous equilibrium 
(vii) Homogeneous equilibrium 
(viii) Hetereogeneous equilibrium K C = [N 2 ] K P = (P N 2 )
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